Hi x_belle4ever_x,
I'm terribly sorry that I didn't answer earlier.
I checked every link for Vampire Knight chapters and there really were a lot of broken links. I'm uploading volume 4 to 8 and will post the links tomorrow. I'm pretty lazy, so I won't upload every single chapter which has a broken link. The links for volume 1, 2 and 3 and chapters 40 to 45 are ok.
About downloading mangas from mangatemple:
At mangatemple, normally, by following the links, you are redirected to an url like
http://www.linkbucks.com/xxxxxxxx and after a certain waiting period (or by skipping the ads) you come to a file hosting site like easy-share, rapidshare etc. There you just have to click "download file" and you'll get your requested chapter. Depending on the site you may have to chose between free and premium download first ( I choose "free"

), have a waiting period again, and/or need to enter a code, displayed on that site to verify that you are human and not a computer programm that downloads files for you.
I hope I could help you.
And sorry again for being so damn late.